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In 1986, there was an effort to create a Usenet recipe book. At the time, I submitted my mother s recipe for kugel, a sweet noodle pudding with vaguely Russian roots. It was one of the three things I knew how to cook. Seventeen years later, I received an email from a friend telling me to do a google.com search on Mom Stern s kugel. The matches returned span multiple continents, imperial and metric measuring systems, at least half a dozen languages, and archives that go back about 20 years. It s the same recipe, now copied so deeply into the fabric of the Internet that I couldn t rescind it if I wanted to. I believe this is the electronic equivalent of the definition of a good kugel: It s so dense it sinks in mercury. Hal

surface area), F is Faraday s constant, I is the ionic strength of the mobile phase, eo is the permittivity of a vacuum, and er is the dielectric constant of the mobile phase. Figure 14.11 shows how the free energy varies with distance between the charged stationary phase and the protein surface. Substituting Eq. 14.29 into Eq. 14.27 and rearranging yields Eq. 14.30: ln k fAp s2 = Ff2 RTeo er g1=2 gf1=Ig1=2 ln f p 14:30

There are several functioning examples of rudimentary global storage repositories on the Internet today. The late, lamented music-sharing service Napster was the first well-known case, and its spiritual descendants (KaZaA, Gnutella, Morpheus, WinMX, Audiogalaxy, and so on) have ensured that this technology will exist far into the future. A recent check of KaZaA found over 3,500,000 active users sharing nearly 800 million files totaling almost six million gigabytes (six petabytes) of data. So, anonymous, global, distributed file sharing is alive and well.

If we apply the analysis from IT urbanization, this is in fact a question of adding the services required to exchange with partners (Figure 4.12) to the flow manager, often extending its hold beyond business IT.

Autonomic computing is a term that IBM is popularizing. It is an approach to self-managed computing systems with a minimum of human interference. The term comes from the body s autonomic nervous system, which controls key functions, such as heartbeats and digestion, without conscious awareness or involvement.

This equation correctly describes the linear dependence of ln k on I 1=2 , and furthermore allows the calculation of the net charge on a protein from the slope of this plot, provided that the surface area (or radius) of the protein is known. The constants in the slope can be evaluated, under conditions of an aqueous mobile phase at 25 C with 0:05 I 0:5 M, so that the net charge, q, is given by q f slope surface area =135g1=2 14:31

22

As computing power, storage capacity, network bandwidth, and society s dependency on computers has increased over the last few years, so has the complexity of computing systems As the number of computers has increased, the need for talented system administrators has increased, too, but the supply of these skilled individuals has not increased significantly Although there are certification programs, there is no real training ground to learn the ropes of system administration Every system administrator we know had to learn on the job (When will a forward-thinking university offer a degree program in computer system administration ) At some point, probably fairly soon, it will become necessary for systems to become much easier to manage so that they do not require significant amounts of routine administration Ideally, they should require no routine administrative tasks like allocation of filesystems, shuffling of computer resources, or job scheduling.

where surface area is in units of (A2) Figure 1412 shows the plots of ln k against I 1=2 obtained for chymotrypsinogen, lysozyme and cytochrome c on a weak cation exchange column at pH 60 Except for the nonlinearity of the chymotrypsinogen plot at low ionic strength, the plots show good linearity over a wide range of I, and Eq 1431 was used to evaluate the net charges of lysozyme and cytochrome c as 106 and 107, respectively Similar experiments to those shown in Fig 1412 have been performed for a large number of proteins at different pH values and using different eluting salts and stationary phases The net charge values calculated from the chromatographic plots, qchr, have been compared to values previously obtained from titration data, qtitr The results of these experiments are shown in Table 14.