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Table 3.5 Comparing Two Sets of Technologies and Their Effects on Downtime after the Same Outage LIFECYCLE PHASE Lost data WITH SUPERIOR PROTECTION Synchronous data replication results in data being up-todate and available at the disaster recovery site. There should be no lost data whatsoever. WITH INFERIOR PROTECTION Weekly full backups that are sent off-site must be retrieved and restored at the remote site. The restore process can take days or weeks. Data written after the most recent weekly backup is lost. System administrators must manually bring up each application at the disaster recovery site. This process could take days. The operations are in degraded mode while the primary site is down. But work can continue normally using systems at the disaster recovery site. If another disaster should occur, the results would be catastrophic. When the primary site has been restored to service, a downtime, similar to the amount of downtime when the outage occurred, will be incurred as data and applications are migrated back.

The monoisotopic mass, calculated using the exact mass of the most abundant isotope of each element, is more useful, especially for high-resolution MS of low molecular weight species For biomolecules and their fragment ions, the most useful value is the average mass The average mass is calculated using elemental atomic weight values that are averaged over all isotopes; this value allows the position of the envelope peak to be predicted13 Table 155 shows examples of nominal, monoisotopic, and average mass values Although the differences between nominal and average values may appear small, especially for elemental species, they become larger as molecular complexity increases and are important in establishing the identities of proteins In particular, site-directed mutagenesis and posttranslational modi cation studies require accurate average mass values to con rm the identities of product proteins.

Through remote clustering, applications are automatically brought up at the disaster recovery site.

The operations are in degraded mode while the primary site is down. But work can continue normally using systems at the disaster recovery site. If another disaster should occur, the results would be catastrophic. When the primary site has been restored to service, a brief amount of downtime, similar to the amount of downtime when the outage occurred, will be incurred as data and applications are migrated back.

For puri ed samples of small molecules studied on low-resolution mass spectrometers, and for singly charged larger molecules, fragment ions are readily identi ed by straightforward calculations using average mass values The presence or absence of observable fragments (including the parent ion) are known to depend on the type.

In truth, of course, the outage lifecycle model is a very simple one. Outages and failures do not occur in a vacuum. While the effects of a second outage that is related to the first are accounted for in the lifecycle s Degraded Mode, one outage can bring about another in less predictable ways. One failure can cause another failure because of the additional load that the first failure puts on some other component for example, a clustered database server that handles all of the load on a single node may run out of log space or suffer from network connection loading problems. The formal analysis for evaluating multiple

The top-down approach Once the BPM project has been launched, and the business processes have been selected for processing, it will be necessary to implement a way of working that will process the complete set of steps, from the initial design of the model for each process right up to the deployment of a version that can be executed in the selected environment..

3

TABLE 15.5. Nominal, Monoisotopic, and Average Mass for Some Elements and Moleculesa Element or Molecule Carbon Hydrogen Nitrogen Oxygen Sulfur Phosphorus Tripeptide C27H29N3O7 Porcine insulin C256H381N65O76S6

failure modes, and how a system moves from one state to another based on the probability of an individual failure, is known as a chain analysis. Chain in this context refers to the sequence of events that take the system from one state to another. If we assume that the first failure of any component in the system is sufficient to cause user-visible disruption and we concentrate on repairing those failures, then we can take a simplified view of the world and treat the overall system health, over time, as a series of single lifecycle events described previously. As mentioned in 2, making sure your system is renewable that it has the same MTBF characteristics after a failure has been repaired will allow you to simplify your view of the outage lifecycle to that of a series of individual events.

In daltons (Da).