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where M is experimentally measured mass of the peak of interest (Da), and the m (Da) value is the mass separation between the maxima of two (symmetrical) closely spaced peaks, as shown in Figure 15.5. Usually, the 10% valley de nition is used to establish whether a peak is separated from another (Fig. 15.5); by this de nition two peaks are considered separated if they coalesce at a maximum intensity of 10% of the peak height. An analogous criterion is the 50% valley de nition; by

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A Data Matrix is a two-dimensional barcode consisting of black and white "cells" or modules arranged in either a square or rectangular pattern, also known as a ...

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4.4.1. Points of departure Since integration solutions now make it possible for different applications to carry out exchanges, their implementation ensures better consistency of services of the enterprise, not only inside its boundaries, but also outside. This is because, as we saw above, the applications of the enterprise are linked to those of partners and suppliers, improving the reactivity and the competitiveness of all the participants (see section 2.7). Most approaches to application integration still address the movement of data between applications, and are therefore still far from completed. In fact, the objectives of integration are primarily business objectives, not just technical milestones, including objectives such as increased competitiveness, improved quality of service, and more efficient management of information exchanges via electronic data exchanges between the various participants. The next step in the

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apparent to the budget holder that this outage is costing his business a lot of money, he will likely approve additional spending to protect against future failures. When he does that, he is nudging the system up the Continuum. The higher a system needs to be on the Continuum, the more it costs to get it there. The higher cost is necessary because in order to achieve higher levels of availability, you need to protect against more varieties of more complicated and less frequently occurring outages.

Figure 15.5. Resolution can be calculated using different de nitions. The more stringent of these is the 10% valley de nition, which is more common in magnetic sector MS.

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this de nition, the resolution calculated from a given set of data is nominally higher. A resolution of R 1000 means that the mass spectrometer can separate an ion at m/z 10,000 from another at 10,010. If the resolution is low, two or more peaks may appear as only one. Alternatively, one isolated symmetrical peak can be used to estimate R. In this case, m can be de ned as the peak width at 5%, or at the 50% level, which is usually referred to as full with at half-maximum (FWHM) as shown in Figure 15.6. In quadrupole and ion trap spectrometers, it is customary to use the unit resolution de nition, which means that each mass can be separated from the next integer mass (500 from 501, 2000 from 2001, etc.). The comparison and conversion between the different resolution de nitions is not trivial, considering that they are strongly dependent on peak shape (Gaussian, triangular, trapezoidal, Lorentzian, etc.).9 Resolution is also used to compare the theoretical (calculated or predicted) mass value to the experimentally observed value. Resolution de nes the peak width, and a parts per million (ppm) error value can be calculated with Eq. 15.8; this allows estimation of the precision of an experimental mass assignment: ppm 106 106 m R M 15:8

3

At about this point in the process, the people who approve budgets get upset because they see that the cost of their critical system is about to rise considerably. They are right. But they should not feel cheated. The system they are buying is going to make money for the enterprise, either through direct income opportunity (for example, e-commerce) or through improvements in efficiency, and so it is natural that there be expenses associated with the system. (Please refer to 5, 20 Key High-Availability Design Principles, #20: Don t Be Cheap, and #19: Assume Nothing for further discussion of the need to spend money to achieve high availability.) Putting additional money into an enterprise s critical systems to increase their availability is often viewed by some as throwing good money after bad. That is not the case. The systems were purchased to perform a particular function. If they are unable to perform that function to an appropriate degree, then the money spent on the systems may be wasted. Instead, consider the additional spending as an investment in the critical systems that run your business. With that in mind, we offer Figure 3.2, which is an attempt to graph investments in availability increases against different levels of availability. Close examination of Figure 3.2 reveals that costs increase until the cost curve nearly flattens out along the top, which represents the highest levels of availability. This is because the highest levels of availability approach but never quite reach 100 percent, which we believe is impossible to achieve over a long period of time.

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